When I want to do 2D cartoons I add these lines in the start of my scene
file:

global_settings {
   post_process {find_edges{10000,.05,1,1,1,rgb 0}}
}
#default {finish {ambient 0.4 diffuse 0.3 brilliance 0}}

It's not perfect, but it works for some cases.

Hope this helps!

Rune
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